I can't tell you when they went to Dacron, but the use of proxylin and related chemicals has been around for a long time. Nitrocellulose is made by processing cellulose (cotton, for example) with nitric acid and sulfuric acid. Nitrocellulose in alcohol or ether produces the plastic proxylin. Proxylin is fast-drying and forms a film, which has many uses. It has been around since before the Civil War, when among other things it was used as a covering for wounds. Since then, these substances have been the basis for artificial leathers, laquers, automotive finishes and explosives. It is the basis of guncotton and flash paper (well known from the magician's toolkit). "Airplane dope" includes things like nitrocellulose, cellulose acetate or other similar chemicals.
Dacron is DuPont's trade name for polyester fiber and the fabrics made from it. Mylar is the same thing, just in film form.
So if you're very diligent you can have a beautiful, resilient, AND explosive Penn Yan!